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Publications
Selected Publications
For a complete list of publications please visit this link
Rajendran, A.*; Shimizu, G. K. H.*; Woo, T. K.* The Challenge of Water Competition in
Physical Adsorption of CO 2 by Porous Solids for Carbon Capture Applications - a short
perspective, Adv. Mater. Accepted.0
Lin, S.; Kedzior, S. A.; Zhang, J.; Yu, M.; Huynh, R. P. S.; Shimizu, G. K. H.*; Trifkovic, M.* A
Superprotonic Membrane Derived from Proton Conducting Metal-Organic Frameworks and
Cellulose Nanocrystals. CHEM (Accepted)
Glavinovic, M.; Perras, J. H.; Gelfand, B. S.; Lin, J. B.; Spasyuk, D. M.; Zhou, W.; Shimizu, G.
K. H.* Microporous Metal-Phosphonates with a Novel Orthogonalized Linker and
Complementary Guests, Chem. Eur. J. 29, 10.1002/chem.202203835 (2023).
Al-Attas, T,; Nabil, S. K.; Zeraati, A. S.; Shiran, H. S.; Alkayyali, T.; Zargartalebi, M.; Tran, T.
Marei, N. N.; Bari, M. A. A.; Lin, H. Q.; Roy, S.; Ajayan,; P. M.; Sinton, D.; Shimizu, G. K.
H,*; Kibria, M. G.* Permselective MOF-Based Gas Diffusion Electrode for Direct
Conversion of CO2 from Quasi Flue Gas, ACS Energy Lett. 107-115 (2022).
Nguyen, T. T. T.; Lin, J. B.; Rajendran, A*.; Shimizu, G. K. H.*, Separation of CO2 and N2 on a
hydrophobic metal organic framework CALF-20, Chem. Eng. J., 442, 136263 (2022).
Lin, J. B.; Nguyen, T. T. T.; Vaidhyanathan, R.; Burner, J.; Taylor, J. M.; Durekova, H.; Akhtar,
F.; Mah, R. K.; Ghaffari-Nik, O.; Marx, S.; Fylstra, N.; Iremonger, S. S.; Dawson, K. W.;
Sarkar, P.; Hovington, P.*; Rajendran, A*.; Woo, T. K.*; Shimizu, G. K. H.* A scalable
metal-organic framework as a durable physisorbent for carbon dioxide capture, Science
374, 1464-1468 (2021).
Lal, G.; Derakhshandeh, M.; Akhtar, F.; Spasyuk, D. M.; Lin, J. B.; Trifkovic, M.*; Shimizu, G.
K. H.* Mechanical Properties of a Metal-Organic Framework formed by Covalent Cross-
Linking of Metal-Organic Polyhedra. J. Am. Chem. Soc. 141, 1045-1053.
DOI: 10.1021/jacs.8b11527 (2019).
Taylor, J. M.*; Dwyer, P. J.; Reid, J. W.; Gelfand, B. S.; Lim, D.; Donoshita, M.; Veinberge, S.
L.; Kitagawa,,H.; Vukotic, V. N.; Shimizu , G. K. H.* Holding open micropores with water:
H-bonded networks supported by hexaaquachromium(III) cations, CHEM, 4, 868–878,
(2018)
Kim, S.; Joarder, B.; Hurd, J. A.; Zhang, J. F.; Dawson, K. W.; Gelfand, B. S.; Wong, N. E.;
Shimizu , G. K. H.* Achieving Superprotonic Conduction in Metal–Organic Frameworks
through Iterative Design Advances. J. Am. Chem. Soc. 140, 1077-1082:
https://doi.org/10.1021/jacs.7b11364 (2018).
Wong, N. E. Ramaswamy, P.; Lee, A. S.; Gelfand, B. S.; Bladek, K. J.; Taylor, J. M.; Spasyuk,
D. M., Shimizu, G. K. H. *Tuning Intrinsic and Extrinsic Proton Conduction in Metal-Organic
Frameworks by the Lanthanide Contraction. J. Am. Chem. Soc. 139, 14676-14683,
https://doi.org/10.1021/jacs.7b07987 (2017).
Joarder, B., Lin, J. B., Romero, Z. & Shimizu, G. K. H. * Single Crystal Proton Conduction
Study of a Metal Organic Framework of Modest Water Stability. J. Am. Chem. Soc. 139,
7176-7179, https://doi.org/10.1021/jacs.7b03397 (2017).
Gelfand, B. S., Huynh, R. P. S., Mah, R. K.; Shimizu, G. K. H. * Mediating Order and
Modulating Porosity by Controlled Hydrolysis in a Phosphonate Monoester Metal–Organic
Framework. Angew. Chem. Int. Ed. 55, 14614-14617,
https://doi.org/10.1002/anie.201607745 (2016).
Ramaswamy, P., Wong, N. E., Gelfand, B. S.; Shimizu, G. K. H. * A Water Stable Magnesium
MOF That Conducts Protons over 10-2 S cm-1. J. Am. Chem. Soc. 137, 7640-7643,
https://doi.org/10.1021/jacs.5b04399 (2015).
Taylor, J. M., Dawson, K. W.; Shimizu, G. K. H. * A water-stable metal-organic framework with
highly acidic pores for proton-conducting applications. J. Am. Chem. Soc. 135, 1193-1196,
https://doi.org/10.1021/ja310435e (2013).
Shimizu, G. K. H. *, Taylor, J. M.; Kim, S. Proton conduction with metal-organic
frameworks. Science 341, 354-355, https://doi.org/10.1126/science.1239872 (2013).
Kim, S., Dawson, K. W., Gelfand, B. S., Taylor, J. M.; Shimizu, G. K. H. * Enhancing proton
conduction in a metal-organic framework by isomorphous ligand replacement. J. Am.
Chem. Soc. 135, 963-966, https://doi.org/10.1021/ja310675x (2013).
Vaidhyanathan, R., Iremonger, S. I.; Shimizu, G. K. H.; * Boyd, P. G.; Alavi, S.; Woo, T. K..
* Competition and cooperativity in CO2 sorption by amine-functionalized metal-organic
frameworks. Angew. Chem. Int. Ed. 51, 1826-1829,
https://doi.org/10.1002/anie.201105109 (2012).
Taylor, J. M., Vaidhyanathan, R., Iremonger, S. S.; Shimizu, G. K. H. * Enhancing water
stability of metal-organic frameworks via phosphonate monoester linkers. J. Am. Chem.
Soc. 134, 14338-14340, https://doi.org/10.1021/ja306812r (2012).
Iremonger, S. S.; Liang, J.M.; Vaidhyanathan, R.; Martens, I.; Shimizu, G.K.H. *; Daff, T;
Aghaji, M.Z.; Yeganegi, S.; Woo, T.K. *; Phosphonate monoesters as carboxylate-like
linkers for metal organic frameworks. J. Am. Chem. Soc. 133, 20048-20051,
https://doi.org/10.1021/ja207606u (2011).
Vaidhyanathan, R., Iremonger, S. I.; Shimizu, G. K. H. *; Boyd, P. G.; Alavi, S.; Woo, T. K.
*. Direct observation and quantification of CO2 binding within an amine-functionalized
nanoporous solid. Science 330, 650-653, https://doi.org/10.1126/science.1194237 (2010).
Taylor, J. M. Mah, R. K.; Moudrakovski, I.; Ratcliffe, C. I.; Vaidhyanathan, R.; Shimizu, G. K.
H.*Facile proton conduction via ordered water molecules in a phosphonate metal-organic
framework. J. Am. Chem. Soc. 132, 14055-14057,
https://doi.org/10.1021/ja107035w (2010).
Shimizu, G. K. H. *, Vaidhyanathan, R.; Taylor, J. M. Phosphonate and sulfonate metal organic
frameworks. Chem. Soc. Rev. 38, 1430-1449, https://doi.org/10.1039/b802423p (2009).
Hurd, J. A., Vaidhyanathan, R., Thangadurai, V., Ratcliffe, C. I., Moudrakovski, I., & Shimizu,
G. K. H. * Anhydrous proton conduction at 150 °c in a crystalline metal-organic
framework. Nature Chemistry 1, 705-710, https://doi.org/10.1038/nchem.402 (2009).
Chandler, B. D.; Enright, G.; Udachin, K.; Pawsey, S.; Ripmeester, J. A.; Cramb, D. T. *;
Shimizu, G. K. H. * Mechanical gas capture and release in a network solid via multiple
single-crystalline transformations. Nature Materials 7, 229-235,
https://doi.org/10.1038/nmat2101 (2008).
Dalrymple, S. A. & Shimizu, G. K. H. * Crystal engineering of a permanently porous network
sustained exclusively by charge-assisted hydrogen bonds. J. Am. Chem. Soc. 129, 12114-
12116, https://doi.org/10.1021/ja076094v (2007).